Aepuru, RadhamanoharRadhamanoharAepuruRao, Ch.N.Ch.N.RaoUdayabhaskar, R.R.UdayabhaskarVennu, DivyaDivyaVennuGaikwad, Vishwajit M.Vishwajit M.GaikwadKumar, VireshVireshKumarPanda, H.S.H.S.PandaAqueveque, PabloPabloAquevequeCao, PeijiangPeijiangCaoMangalaraja, Ramalinga ViswanathanRamalinga ViswanathanMangalaraja2026-10-192026-10-192020-12-10Aepuru, Radhamanohar; Rao, Ch.N.; Udayabhaskar, R.; Vennu, Divya; Gaikwad, Vishwajit M.; Kumar, Viresh; Panda, H.S.; Aqueveque, Pablo; Cao, Peijiang; Mangalaraja, Ramalinga Viswanathan (2020-12-10). Polarization-Induced Quantum-Mechanical Charge Transfer in Perovskite-Graphene Nanocomposites with Superior Electro-optic Switching Modulation. JOURNAL OF PHYSICAL CHEMISTRY C, 124 (49), 26648-26658. https://doi.org/10.1021/acs.jpcc.0c080691932-74471932-7455https://hdl.handle.net/20.500.12740/25215Understanding the concept of light-matter interaction in organic-inorganic nanostructures such as graphene and metal-halide perovskites has been explored to realize photonic and optoelectronic devices. The strong light-matter interaction and impressive performance achieved by tuning the optical/electrical properties have enabled them as potential candidates for optoelectronic applications. In this perspective, we report the synthesis of metal-halide perovskite nanocomposites by incorporation of graphene sheets into the perovskite framework, which exhibits a significant enhancement in electro-optic (E-O) switching modulation. The carrier dynamics in the nanocomposite is investigated using time-resolved luminescence and broadband dielectric spectroscopy studies to get insights into the carrier relaxation and transfer mechanisms. The presence of graphene in the perovskite nanocomposites induced dielectric polarization with a strong electrical conduction and a nonlinear dielectric behavior with negative permittivity at the percolation threshold concentration because of the large resonance derived from the plasmonic oscillations of delocalized charges. A custom-designed optical fiber integrated with nanocomposites is scrutinized to explore the light modulation and E-O sensitivity under an applied electrical field. The E-O interference that leads to phase modulation of light by change in the refractive index of the graphene-CsPbBr3 nanocomposites resulted in a higher E-O sensitivity of 18 nm/V than those of CsPbBr3 nanostructures.enArticulohttps://doi.org/10.1021/acs.jpcc.0c08069