The design of multifunctional materials for energy storage and conversion systems is vital in addressing present global energy issues. In this work, we have prepared a highly active and economical hybrid material comprising ZnO and Nb2O5, integrated with g-C3N4 (Nb@ZGCN) through the simple chemical method followed by calcination process. The resultant Nb@ZGCN electrode delivered a specific capacitance of 122.3 F g(-1) at a current density of 1 A g(-1) and maintained 71% of its initial value at a current density of 4 A g(-1) in a 6 M KOH electrolyte. This hybrid electrode exhibited superb cyclic stability of 105% even after 2000 cycles at 4 A g(-1) with an increased coulomb efficiency than the first cycle which is close to 100%. Additionally, the prepared hybrid material was further applied for electrocatalytic hydrogen evolution reaction (HER), delivering a small overpotential of 252.1 mV to achieve a current rate of 10 mA cm(- 2) along with long-term durability in a 1 M KOH medium. The synergistic interaction between the ZnO, Nb2O5 and graphitic carbon nitride in the hybrid structure leads to abundant electroactive sites that remarkably improve the supercapacitive and HER activities. These results suggest that the developed hybrid material can be further exploited as an electrode material for supercapacitor and water splitting applications. C1 [Vijay, Aromal M.] Noorul Islam Ctr Higher Educ, Dept Phys, Kumaracoil 629180, Tamil Nadu, India. [Kavinkumar, T.] Karpagam Acad Higher Educ, Ctr Energy & Environm, Dept Phys, Coimbatore 641021, India. [Gobalakrishnan, S.] Rajalakshmi Engn Coll, Dept Phys, Chennai 602105, India. [Chidhambaram, N.] Rajah Serfoji Govt Coll Autonomous, Dept Phys, Thanjavur 613005, Tamil Nadu, India. [Asaithambi, Perumal] Jimma Univ, Jimma Inst Technol, Fac Civil & Environm Engn, POB 378, Jimma, Ethiopia. [Srinivasan, R.] Ramco Inst Technol, Dept Phys, Rajapalayam 626117, Tamilnadu, India. [Thirumurugan, Arun] Univ Atacama, Sede Vallenar,Ave Costanera 105, Vallenar 1612178, Chile. C3 Karpagam Academy of Higher Education (KAHE); Rajalakshmi Engineering College; Jimma University; Universidad de Atacama