Functionalization of the bis-(o-mercaptobenzoato)-cis-dioxomolibdato(VI) anion, [MoO2 (o-SC6H4COO)2]2-, with p-substituted arylhydrazines, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, NO2. X-ray structure of [Et3NH]2[Mo(NNC6H4-p-Cl)2(o-SC6H4COO)2]

Kao, JL; Carrillo, D; Vega, A; Garland, MT

doi:https://doi.org/10.4067/s0366-16442002000100003

Functionalization of the bis-(o-mercaptobenzoato)-cis-dioxomolibdato(VI) anion, [MoO2 (o-SC6H4COO)2]2-, with p-substituted arylhydrazines, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, NO2. X-ray structure of [Et3NH]2[Mo(NNC6H4-p-Cl)2(o-SC6H4COO)2]

Journal

BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA

Date Issued

2002-03

Author(s)

Kao, JL

Carrillo, D

Vega, A

Garland, MT

DOI

https://doi.org/10.4067/s0366-16442002000100003

Abstract

In acetonitrile, the cis-[MoO2]2(+) group present in the anionic complex [MoO2(o-SC6H4COO) (2)](2-), can be functionalized under mild conditions by reaction with arylhydrazines, p-R-C6H4NHNH2. The resulting ionic complexes have been formulated as [Et3NH](2)[Mo(NNC6H4-p-R)(2)(o-SC6H4COO)(2)], R=H, [Et3NH](2)[1]; Me, [Et3NH](2)[11]; MeO, [Et3NH](2)[111]; Cl, [Et3NH](2)[IV];NO2, [Et3NH](2)[V] characterized by spectroscopic methods and, additionally, in the case of complex [Et3NH](2)[IV], by single crystal X-ray diffraction. The aryldiazenido ligands, occupying mutually cis positions, adopt the singly bent geometry.

Subjects

organodiazenido

aryldiazenido

diazenido

molybdenum complexes

o-mercaptobenzoate

molecular structure

Repositorio Académico Institucional

Functionalization of the bis-(o-mercaptobenzoato)-cis-dioxomolibdato(VI) anion, [MoO2 (o-SC6H4COO)2]2-, with p-substituted arylhydrazines, R-p-C6H4NHNH2, R=H, Me, MeO, Cl, NO2. X-ray structure of [Et3NH]2[Mo(NNC6H4-p-Cl)2(o-SC6H4COO)2]